Poly[diaqua-μ-oxalato-μ-pyrazine-2-carboxylato-lanthanum(III)]

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Poly[diaqua-μ-oxalato-μ-pyrazine-2-carbox­yl­ato-lanthanum(III)]

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The title compound, [Cu4(C2O4)2(N3)4(C5H9N3)2]·0.9H2O, contains a tetranuclear Cu(II)-based molecule composed of two oxalate-bridged Cu(II) dimers linked through end-on azide ions and related by an inversion center. The tetranuclear unit contains two crystallographically independent Cu(II) ions. One Cu(II) ion coordinates to two N atoms of a histamine mol-ecule, two O atoms of a bridging oxalat...

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The title complex, [Dy(C(8)H(6)NO(4))(C(2)O(4))(H(2)O)](n), is a dysprosium coordination polymer with mixed anions and was obtained under hydrothermal conditions. In the structure, the oxalate and 5-amino-isophthalate ligands link the dysprosium ions, building up a two-dimensional metal-organic framework parallel to the (10) plane. These sheets are further connected through O-H⋯O, N-H⋯O and C-H...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808041664